The effect of oxygen and water vapor partial pressures on the total conductivity of BaCe0.7Zr0.1Y0.2O3–Δ

Abstract

The effect of oxygen and water vapor partial pressure on the total conductivity of the proton-conducting BaCe0.7Zr0.1Y0.2O3–δ material is investigated in the present work. Single-phase and dense ceramic materials have been successfully obtained using the citrate–nitrate synthesis method. The contributions of partial conductivities (hole, oxygen-ionic, protonic) are evaluated based on electrical and emf measurements. At 900 °C in air atmosphere, ionic and hole conductivities almost equivalently contribute to the total conductivity, while in reducing temperatures, the transport of the studied material becomes ionic; the predominant protonic transport (tH ≈ 1) realizes under wet hydrogen atmospheres at temperatures below 700 °C. Based on the measurements of total conductivity as a function of water vapor partial pressure, it is found that the increase of conductivity in reducing atmospheres is associated with the growth of proton conductivity. A non-monotonic change of total conductivity in oxidizing atmospheres is caused by the competing effects, namely decreasing the hole conductivity and increasing the protonic one. © 2017, Springer-Verlag Berlin Heidelberg.