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Application of Solid oxide proton-conducting electrolytes for amperometric analysis of hydrogen in H-2+N-2+H2O gas mixtures
(2014)Amperometric hydrogen sensors based on proton-conducting solid electrolytes of La0.95Sr0.05YO3, CaTi0.95Sc0.05O3 and CaZr0.9Sc0.1O3 compositions are prepared and investigated in the present work. The influence of the sensor ... -
BaCeO3: Materials development, properties and application
(2014)The characteristic of a number of oxide materials, which include BaCeO3-systems, is their ability to show the proton conductivity along with oxygen-ion conductivity. Such atypical behavior for other oxides attracts great ... -
Conductivity of Gd-doped BaCeO3 protonic conductor in H2-H2O-O2 atmospheres
(2013)This work proposes a radically new simple method of evaluation of the proton conductivity based on measurement of the conductivity of ceramic materials depending on the oxygen partial pressure (pO2) at a gradual transition ... -
Cu and Gd co-doped BaCeO3 proton conductors: Experimental vs SEM image algorithmic-segmentation results
(2014)Segmentation algorithms for the quantitative description of the surface microstructure and the evaluation of the grain-boundary conductivity of ceramic materials surface using SEM microphotographs analysis was developed ... -
The effect of cobalt oxide addition on the properties of gadolinium doped barium cerate
(2009)In the present work the effect of cobalt oxide addition on the density and on the electrical properties of gadolinium doped barium cerate is investigated. A series of BaCe0.9-xGd0.1CoxO3-δ (?=0.00, 0.01, 0.03, 0.05, 0.07, ... -
Electrodes for solid electrolyte sensors for the measurement of CO and H-2 content in air
(2013)Using a test-tube made of yttria-stabilized zirconia (YSZ) as a measuring cell, different simple oxides MexOy (M = Zn, Sn, Cr, In), complex oxides with perovskite structure (La0.8Sr0.2CrO3 and La0.6Sr0.4MnO3) and silver ... -
Ethanol Utilization In Solid Oxide Fuel Cells: A Thermodynamic Approach
(1999)A thermodynamic analysis of electrical power generation in ethanol fueled solid oxide fuel cells (SOFCs) was made in the temperature range between 800-1200 K at atmospheric total pressure. A SOFC was considered being fed ... -
High temperature electrolyzer based on solid oxide co-ionic electrolyte: A theoretical model
(2007)In the present work a theoretical model of a solid oxide electrolyzer based on an electrolyte having both oxygen ion and proton conductivity is considered. The main parameters of the electrolytic process and an electrolyzer ... -
Hydrogen production aided by new (1-x) SrTi0.5Fe0.5O3-delta-xCe(0.8)(Sm0.8Sr0.2)(0.2)O2-delta(MIEC) composite membranes
(2014)In the present work, composite materials of the type (1-x)SrTi0.5Fe0.5O3-delta-xCe(0.8)(Sm0.8Sr0.2)(0.2)O2-delta (with x = 0, 0.25, 0.5, 0.75 and 1) are obtained by the two step solid state technique. Their transport ... -
Influence of Cu on the properties of gadolinium-doped barium cerate
(2008)In the present work the effect of copper oxide addition on the densification behavior and electrical conductivity of BaCe1-xGdxO3-delta (BCG) type ceramics is investigated. Small addition (1 mol%) of this sintering additive ... -
Influence of sintering additives of transition metals on the properties of gadolinium-doped barium cerate
(2008)In the present work the effect of MOx (where M =Cu, Ni, Zn, Fe, Co, Ti) addition on the densification behavior and electrical conductivity of BaCe(0.9)d(0.1)O(3-delta) ceramics is investigated. It was found that the small ... -
Insights on thermal and transport features of BaCe0.8-xZrxY0.2O3-delta proton-conducting materials
(2015)BaCe0.8-xZrxY0.2O3-delta-based materials (BCZYx, 0 <= x <= 0.8) are obtained through a modified citrate-nitrate combustion method at 1150 degrees C with following sintering at 1450 degrees C. Then their thermomechanical ... -
Investigation of the protonic conduction in Sm doped BaCeO3
(2008)In the present work the structural and electrical properties of samarium-doped barium cerate perovskites of BaCe1-xSmxO3-delta formula (with x=0-0.2), prepared by following the solid state reaction method, are investigated. ... -
Investigation of the structural and electrical properties of Co-doped BaCe0.9Gd0.1O3-delta
(2011)In the present work the effect of cobalt oxide addition on the density and on the electrical properties of gadolinium-doped barium cerate is investigated. A series of BaCe0.9-xGd0.1CoxO3-delta (x = 0.00, 0.01, 0.03, 0.05, ... -
New mixed ionic-electronic composite materials based on SRTI0.5FE0.5O3-Δ and CE0.8(SM0.8SR0.2)0.2O2-Δ
(2013)The crystal, electrical and electrochemical properties of the new composite materials of (1-x)SrTi0.5Fe0.5O3-δ-xCe0.8(Sm0.8Sr0.2)0.2O2-δ (0≤x≤1, Δx= 0.25) prepared by solid phase method. Composites have no phase interaction. ... -
Novel composite solid state electrolytes on the base of BaCeO3 and CeO2 for intermediate temperature electrochemical devices
(2013)In the present work, nano-sized powders of (1-x)Ce0.8Sm0.2O2-delta-xBaCe(0.8)Sm(0.2)O(3-delta) (x = 0, 0.3, 0.5, 0.7 and 1) were obtained by solution combustion synthesis (self-combustion synthesis, SCS) method of nitrate ... -
Polarization study of Fe|BaCe<inf>0.5</inf>Zr<inf>0.3</inf>Y<inf>0.08</inf>Yb<inf>0.08</inf>Cu<inf>0.04</inf>O<inf>3-δ</inf>|Fe electrochemical cells in wet H<inf>2</inf> atmosphere
(2015)In the present work, the steady-state current-overpotential characteristics of the Fe|BaCe<inf>0.5</inf>Zr<inf>0.3</inf>Y<inf>0.08</inf>Yb<inf>0.08</inf>Cu<inf>0.04</inf>O<inf>3-δ</inf>|Fe interface as a function of the ... -
A simple and low-cost amperometric sensor for measuring H<inf>2</inf>, CO, and CH<inf>4</inf>
(2015)The architecture and the operational features of a simple and low-cost amperometric sensor based on 0.91 ZrO<inf>2</inf> + 0.09 Y<inf>2</inf>O<inf>3</inf> solid electrolyte, used for measuring H<inf>2</inf>, CO, and ... -
Single phase materials based on Co-doped SrTiO3 for mixed ionic-electronic conductors applications
(2012)In the present work the effect of cobalt oxide addition on the structural and electrical properties of strontium titanate is examined. The SrTi1-xCoxO3-delta (0 <= x <= 0.4) samples were synthesized according to solid state ... -
A SOFC based on a co-ionic electrolyte
(2004)In the present work the operation of a SOFC based on a co-ionic electrolyte is considered. The special case of ion transport in a co-ionic electrolyte is analyzed. It is shown that partial ion currents do not correspond ...