Όλο το DSpace

Εμφάνιση απλής εγγραφής

Bi- and tri-metallic Pt-based anode catalysts for direct ethanol fuel cells

dc.creatorZhou, W. J.en
dc.creatorLi, W. Z.en
dc.creatorSong, S. Q.en
dc.creatorZhou, Z. H.en
dc.creatorJiang, L. H.en
dc.creatorSun, G. Q.en
dc.creatorXin, Q.en
dc.creatorPoulianitis, K.en
dc.creatorKontou, S.en
dc.creatorTsiakaras, P.en
dc.date.accessioned2015-11-23T10:55:00Z
dc.date.available2015-11-23T10:55:00Z
dc.date.issued2004
dc.identifier10.1016/j.jpowsour.2003.12.040
dc.identifier.issn3787753
dc.identifier.urihttp://hdl.handle.net/11615/34898
dc.description.abstractIn the present work, several Pt-based anode catalysts supported on activated carbon XC-72R were prepared by using a novel method, characterized and tested. XRD analysis and TEM images indicated that all of anode catalysts consist of uniform nanosized particles with sharp distribution and that the Pt lattice parameter becomes shorter with the addition of Ru and Pd and bigger with the addition of Sn and W. Cyclic voltammetry (CV) measurements and single direct ethanol fuel cell (DEFC) tests jointly showed that Sn, Ru and W can enhance ethanol electro-oxidation activity of Pt in the following order: Pt 1Sn1/C > Pt1Ru1/C > Pt 1W1/C > Pt1Pd1/C > Pt/C. The Pt1Ru1/C catalyst was modified with Mo, W and Sn, respectively. It was found that the DEFCs performances were improved with these modified Pt1Ru1/C catalysts as anode catalysts. This distinct DEFC performance behavior is attributed to the so-called bifunctional mechanism and to the electronic interaction between Pt and additives. © 2004 Elsevier B.V. All rights reserved.en
dc.source.urihttp://www.scopus.com/inward/record.url?eid=2-s2.0-2342483909&partnerID=40&md5=513a080574ef0a253835dd81f3ec15bb
dc.subjectBi-metallic and tri-metallic catalystsen
dc.subjectDirect ethanol fuel cellsen
dc.subjectEthanol energyen
dc.subjectAnodesen
dc.subjectCatalystsen
dc.subjectCyclic voltammetryen
dc.subjectEthanolen
dc.subjectLattice constantsen
dc.subjectOxidationen
dc.subjectTransmission electron microscopyen
dc.subjectX ray diffraction analysisen
dc.subjectBimetallic catalystsen
dc.subjectTrimetallic catalystsen
dc.subjectFuel cellsen
dc.titleBi- and tri-metallic Pt-based anode catalysts for direct ethanol fuel cellsen
dc.typejournalArticleen


Αρχεία σε αυτό το τεκμήριο

ΑρχείαΜέγεθοςΤύποςΠροβολή

Δεν υπάρχουν αρχεία που να σχετίζονται με αυτό το τεκμήριο.

Αυτό το τεκμήριο εμφανίζεται στις ακόλουθες συλλογές

Εμφάνιση απλής εγγραφής