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dc.creatorLi, W. Z.en
dc.creatorSong, S. Q.en
dc.creatorZhou, W. J.en
dc.creatorSun, G. Q.en
dc.creatorXin, Q.en
dc.creatorPoulianitis, C.en
dc.creatorTsiakaras, P.en
dc.date.accessioned2015-11-23T10:37:43Z
dc.date.available2015-11-23T10:37:43Z
dc.date.issued2005
dc.identifier10.1007/BF02430409
dc.identifier.issn9477047
dc.identifier.urihttp://hdl.handle.net/11615/30278
dc.description.abstractTwo Pt/C catalysts with different particle sizes (Pt/C: 2.5 nm, Pt/C-700Ar: 5.1 nm) were investigated by applying a half-cell configuration - rotating disk electrode (RDE) technique in H2SO4 aqueous solutions in the absence of or in the presence of methanol with different concentrations. Pt/C catalyst exhibited higher mass activity in H2SO4 aqueous solution without methanol and slightly lower mass activity in H 2SO4 plus 0.1 mol/L CH3OH in comparison with that of Pt/C-700Ar catalyst. On the contrary, single direct methanol fuel cell (DMFC) tests showed that Pt/C exhibited higher oxygen reduction reaction (ORR) activity and better cell performance, mainly due to the different kinds of electrolyte properties. Furthermore, it suggested that a better single DMFC performance could be obtained with a smaller particle size Pt-based cathode catalyst.en
dc.sourceIonicsen
dc.source.urihttp://www.scopus.com/inward/record.url?eid=2-s2.0-33645505920&partnerID=40&md5=b4276296d5da517c1d3c7bf43c19e52a
dc.titleDirect methanol fuel cells: The influence of methanol on the reduction of oxygen over Pt/C catalysts with different particle sizesen
dc.typejournalArticleen


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