Direct methanol fuel cells: The influence of methanol on the reduction of oxygen over Pt/C catalysts with different particle sizes
dc.creator | Li, W. Z. | en |
dc.creator | Song, S. Q. | en |
dc.creator | Zhou, W. J. | en |
dc.creator | Sun, G. Q. | en |
dc.creator | Xin, Q. | en |
dc.creator | Poulianitis, C. | en |
dc.creator | Tsiakaras, P. | en |
dc.date.accessioned | 2015-11-23T10:37:43Z | |
dc.date.available | 2015-11-23T10:37:43Z | |
dc.date.issued | 2005 | |
dc.identifier | 10.1007/BF02430409 | |
dc.identifier.issn | 9477047 | |
dc.identifier.uri | http://hdl.handle.net/11615/30278 | |
dc.description.abstract | Two Pt/C catalysts with different particle sizes (Pt/C: 2.5 nm, Pt/C-700Ar: 5.1 nm) were investigated by applying a half-cell configuration - rotating disk electrode (RDE) technique in H2SO4 aqueous solutions in the absence of or in the presence of methanol with different concentrations. Pt/C catalyst exhibited higher mass activity in H2SO4 aqueous solution without methanol and slightly lower mass activity in H 2SO4 plus 0.1 mol/L CH3OH in comparison with that of Pt/C-700Ar catalyst. On the contrary, single direct methanol fuel cell (DMFC) tests showed that Pt/C exhibited higher oxygen reduction reaction (ORR) activity and better cell performance, mainly due to the different kinds of electrolyte properties. Furthermore, it suggested that a better single DMFC performance could be obtained with a smaller particle size Pt-based cathode catalyst. | en |
dc.source | Ionics | en |
dc.source.uri | http://www.scopus.com/inward/record.url?eid=2-s2.0-33645505920&partnerID=40&md5=b4276296d5da517c1d3c7bf43c19e52a | |
dc.title | Direct methanol fuel cells: The influence of methanol on the reduction of oxygen over Pt/C catalysts with different particle sizes | en |
dc.type | journalArticle | en |
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