dc.creator | Giannopoulou, D. P. | en |
dc.creator | Pirmettis, I. | en |
dc.creator | Pelecanou, M. | en |
dc.creator | Komiotis, D. | en |
dc.creator | Sagnou, M. | en |
dc.creator | Benaki, D. | en |
dc.creator | Raptopoulou, C. P. | en |
dc.creator | Terzis, A. | en |
dc.creator | Papadopoulos, M. S. | en |
dc.date.accessioned | 2015-11-23T10:28:09Z | |
dc.date.available | 2015-11-23T10:28:09Z | |
dc.date.issued | 2007 | |
dc.identifier | 10.1016/j.ica.2007.04.038 | |
dc.identifier.issn | 0020-1693 | |
dc.identifier.uri | http://hdl.handle.net/11615/27918 | |
dc.description.abstract | Neutral. hexacoordinated "3 + 2" mixed ligand oxorhenium (1) and oxotechnetium (2) complexes of the general formula MO [SNO][NN]. where M = Re or Tc-99, SNO is 2-mercaptoethyl-N-glycine and NN is 2,2'-bipyridine (bpy), were synthesized by simultaneous action of the tridentate SNO and the bidentate NN ligand on ReOCl3(PPh3)(2) or (TcO)-Tc-99-gluconate precursors in a 1: 1: 1 molar ratio. Both complexes were characterized by elemental analysis, IR and NMR spectroscopy. X-ray structure determination of rhenium complex I revealed a distorted octahedral coordination geometry where the SNO donor atoms of the tridentate ligand and one bpy nitrogen atom occupy the equatorial positions of the octahedron, whereas the second bpy nitrogen atom and the oxo-group fill the apical positions. (c) 2007 Elsevier B.V. All rights reserved. | en |
dc.source | Inorganica Chimica Acta | en |
dc.source.uri | <Go to ISI>://WOS:000248733200018 | |
dc.subject | rhenium | en |
dc.subject | technetium | en |
dc.subject | mixed ligand complexes | en |
dc.subject | crystal structures | en |
dc.subject | DONOR ATOM SET | en |
dc.subject | NUCLEAR-MEDICINE | en |
dc.subject | CHEMISTRY | en |
dc.subject | TECHNETIUM | en |
dc.subject | RHENIUM | en |
dc.subject | TC-99M | en |
dc.subject | RADIOPHARMACEUTICALS | en |
dc.subject | 2,2'-BIPYRIDINE | en |
dc.subject | DERIVATIVES | en |
dc.subject | STABILITY | en |
dc.subject | Chemistry, Inorganic & Nuclear | en |
dc.title | Synthesis and structural characterization of neutral "3+2" oxorhenium and oxotechnetium complexes of the 2-mercaptoethyl-N-glycine (SNO)/2,2 '-bipyridine (NN) mixed ligand system | en |
dc.type | journalArticle | en |