Identification of catalytic converter kinetic model using a genetic algorithm approach

Abstract

The need to deliver fast-in-market and right-first-time design for ultra-low-emission vehicles at a reasonable cost is driving the automotive industries to invest significant manpower in computer-aided design and optimization of exhaust after-treatment systems. To serve the above goals, an already developed engineering model for the three-way catalytic converter kinetic behaviour is linked with a genetic algorithm optimization procedure, for fast and accurate estimation of the set of tuneable kinetic parameters that describe the chemical behaviour of each specific washcoat formulation. The genetic-algorithm-based optimization procedure utilizes a purpose-designed performance measure that allows an objective assessment of model prediction accuracy against a set of experimental data that represent the behaviour of the specific washcoat formulation over a typical legislated test procedure. The identification methodology is tested on a demanding case Study, and the best-fit parameters demonstrate high accuracy in matching the measured test data. The results are definitely more accurate than those Usually obtained by manual or gradient-based tuning of the parameters. Moreover, the set of parameters identified by the genetic algorithm methodology is proven to describe in a valid way the chemical kinetic behaviour of the specific catalyst, and this is tested by the successful prediction of the performance of a smaller-size converter. The parameter estimation methodology developed fits in an integrated computer-aided engineering methodology assisting the design optimization of catalytic exhaust systems that extends all the way through from model development to parameter estimation, and quality assurance of test data.